Collecting Data on Particulate Matter
Before undertaking air monitoring for Particulate Matter (PM) identify the end goals of monitoring for your community. Monitoring airborne particles can be prohibitively expensive and data that is actionable for regulators can take years to collect. To be efficient, the accuracy and precision of collected data should be appropriate for its end use -- not all data needs to be of regulatory quality in order to be useful. For example, a community may want to collect data to: highlight a problem for the purposes of community mobilization identify emissions hotspots for more monitoring identify key times for visual monitoring compel industry to pay for community monitors to become certified in visual monitoring (Smoke School). compel regulatory monitoring through screening data document a violation of national air quality standards
Airborne particles are clustered into three rough size ranges, or modes, of particles in the air: dust, droplets, and ultrafine particles. While droplets and ultrafines are largely combustion by-products, dust is broken off of larger materials. No single method of PM monitoring method all categories.
Dust is the most established particle mode to monitor. However, dust is ubiquitous, so industrial dust emissions can be difficult to trace back to their source.
Droplets are difficult to monitor. In real-time optical PM monitors, humidity and temperature effects interfere substantially with measurements. Humidity also affects filter-based PM monitors, and questions about allowable water content in droplets is actively debated. Read more on the NAAQS.
The study of ultrafine particles is fairly new. There are no regulatory categories that apply to ultrafines, and no inexpensive means to monitor them. Exposure to ultrafine particles is associated with proximity to combustion, especially of diesel and marine fuels, since most ultrafines are formed through atmospheric reactions of gases.
pg 27 ehp_student_edition_lesson_particles_size_makes_all_the_difference_508.pdf
Due to the varied and significant challenges of accurate monitoring, it is important to determine the data quality (accuracy and precision) needed for a specific research or advocacy end-goals.
Proposed EPA precision categories for citizen monitoring
State and federal regulators are empowered make judgements based on visual assessments of particle pollution, but at present regulators have no statutory guidance or authority to interact with PM data collected with instruments other than their (very expensive) regulatory monitors or on timescales shorter than annually. This can lead to curt rejections of scientifically sound data. Federal regulators recognize this issue and are working to propose categories of precision for community-collected data, as discussed in the Air Sensor Guidebook:
These categories are prospective (except for regulatory monitoring, Category V) and should only be treated as guidelines for technologies in development.
Prompting action to address airborne particles
Given that regulators are currently unlikely to make judgements based any data other than visual monitoring and regulatory monitoring, community-based PM data, in isolation, ae likely to be ineffective at prompting official enforcement. Thus, community-collected PM data needs to be accompanied by strong advocacy to prompt further investigation or leverage publicity and public relations. For information about best practices for developing a community environmental monitoring study, see this wiki. Pathways for community-based monitoring to be effective include:
highlight a problem for the purposes of community organizing and mobilization identify emissions hotspots for more monitoring identify key times for visual monitoring compel industry to pay for community monitors to become certified in visual monitoring (Smoke School). compel regulatory monitoring through screening or suggestive data
Regulatory grade PM monitoring
Regulatory monitors cost $20-60,000 to buy, ~$100/day to analyze, and require 1-3 years of data. It is also important to note that a failure to demonstrate an exceedance of PM2.5 or PM10 standard limits does not necessarily indicate safe conditions. Particles that are of the respirable size-fraction, which have severe health consequences, are mostly excluded from PM2.5 measurements and are not differentiated (or acknowledged) in PM10 measurements. For more information, please read this wiki. Additionally, the composition of particles is not routinely determined, so particularly damaging substances may cause negative health impacts at permissible particle concentrations. For example, airborne silica can be dangerous at 5-10% of regulatory limits on particle concentration.
A visible emission is any visible airborne particles resulting from a process. Visible emissions are correlated with respirable particles, and can be measured by their effects on the opacity of the air. Opacity can be monitored through visual assessment with only a stopwatch. Opacity is expressed as the percentage of light that is scattered or blocked by emissions. Examples of pollutants that change opacity are smoke stack emissions and fugitive dust.
Certifying community observers in EPA Method 9 can be written into a facility’s permits, read more in advocacy leverage points. Read more about visual emissions and certification programs in the visual particulate matter wiki.
Types of monitoring equipment
Most monitors give a mass-based particle concentration for all particles in a size category, meaning they do not differentiate between the relative mass contribution of different sizes of particles within that category. Only systems that capture and save particulate matter can identify, or ‘speciate’ particles by size or elemental composition.
Used for: regulatory monitoring, supplementary monitoring
Filter-based systems can collect particles for laboratory methods of speciation, and are the basis of Federal Reference Methods. Data can only be analyzed after collection, not in real-time. Usually samples are collected over a 24-hour period and the weighted average concentration (by mass) for that 24-hours is produced. Filter-based gravimetric systems are usually the most precise measurements of PM.
Used for: personal exposure monitoring, supplementary monitoring, hotspot identification, hotspot characterization, education
Optical electronic systems offer the possibility of real-time particle counts which are valuable for hotspot identification, recording short-term high emissions events, and identifying when air may pose a health threat. Their data is significantly affected by humidity though. More precise monitors usually include a filter-based system to correct data after collection, such as what Public Lab plans to do by collocating optical systems with passive monitors.
Used for: personal exposure monitoring, supplementary monitoring, education, hotspot characterization, education
Passive systems have no moving parts and are easy to deploy for long-term monitoring without electricity. They can approach the precision of regulatory monitoring and are within the accuracy and precision ranges necessary for supplementary monitoring. Passive monitors generally require longer sample collection periods (3-10 days) than active filter-based monitoring, and are better used to characterize hotspots than to identify them.
Passive monitors collect particles onto filters or slides, so there is the opportunity to do some limited speciation analyses of particles.